Ethanol decomposition over Pd-based catalyst in the presence of steam

被引：31

作者：

Galvita, VV

Belyaev, VD

Semikolenov, VA

Tsiakaras, P

Frumin, A

Sobyanin, VA ^{[1
]}

机构：

[1] Boreskov Inst Catalysis, Novosibirsk 630090, Russia

[2] Univ Thessaly, Dept Mech & Ind Engn, Volos 38334, Volos, Greece

[3] Novosibirsk State Univ, Novosibirsk 630090, Russia

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 2002年 / 76卷 / 02期

关键词：

ethanol; decomposition; Pd-based catalyst;

D O I：

10.1023/A:1016500431269

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Catalytic decomposition of ethanol in the presence of steam over Pd supported on a porous carbonaceous material was studied. XPS and TEM were used for the catalyst characterization. Experiments were performed under atmospheric pressure, temperature of 320-360degreesC and H2O/C2H5OH molar ratio 8.1. It was found that the catalyst exhibited a high activity and long-term stability for the ethanol decomposition into a gas mixture containing carbon oxides, methane and hydrogen.

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页码：343 / 351

页数：9

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