Rotational polymorphism in 2-naphthalenethiol SAMs on Au(111)

被引:47
作者
Jiang, Peng
Nion, Aymeric
Marchenko, Alexandr
Piot, Luc
Fichou, Denis [1 ]
机构
[1] CEA Saclay, CNRS,CEA, UPMC,LRC Nanostruct & Semicond Organ, SPCSI,DRECAM, F-91191 Gif Sur Yvette, France
[2] Natl Ctr Nanosci & Technol, Beijing 100080, Peoples R China
关键词
D O I
10.1021/ja063060z
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We evidence by STM that 2-naphthalenethiol self-assembled monolayers formed at the n-tetradecane/Au(111) interface coexist as two structural phases which both possess molecules into two different orientations (standing and lying). Such a rotational polymorphism is observed and understood at the molecular level for the first time. Copyright © 2006 American Chemical Society.
引用
收藏
页码:12390 / 12391
页数:2
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