Supertetrahedral decametallic Ni(II) clusters directed by μ6-tris-alkoxides

被引：48

作者：

Shaw, R

Tidmarsh, IS

Laye, RH

Breeze, B

Helliwell, M

Brechin, EK

Heath, SL

Murrie, M

Ochsenbein, S

Güdel, HU

McInnes, EJL

机构：

[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

[2] Univ Bern, Dept Chem, CH-3000 Bern 9, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 12期

关键词：

D O I：

10.1039/b403876b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report the syntheses, structures and magnetic properties of two decametallic Ni(II) clusters with unprecedented supertetrahedral cores, stabilised by the (hitherto unobserved) mu(6)-coordination modes of the tris-alkoxides {MeC(CH2O)(3)}(3)(-) and {C6H9O3}(3-).

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收藏

页码：1418 / 1419

页数：2

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