Soft Functional Materials Induced by Fibrillar Networks of Small Molecular Photochromic Gelators

被引:82
作者
Bhattacharya, Santanu [1 ,2 ]
Samanta, Suman K. [1 ]
机构
[1] Indian Inst Sci, Dept Organ Chem, Bangalore 560012, Karnataka, India
[2] Indian Inst Sci, Jawaharlal Nehru Ctr Adv Sci Res, Chem Biol Unit, Bangalore 560012, Karnataka, India
关键词
PHASE-TRANSITION; ORGANOGELS; GELATION; GELS; MIXTURES; DESIGN; MATTER;
D O I
10.1021/la901017u
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
Low-molecular-mass organogelators (LMOGs) based on photochromic molecules aggregate in selected solvents to form gels through various spatio-temporal interactions. The factors that control the mode of aggregation of the chromophoric core in the LMOGs during gelation, gelation-induced changes in fluorescence, the formation of stacked superstructures of extended pi-conjugated systems, and so forth are discussed with selected examples. Possible ways of generating various light-harvesting assemblies are proposed, and some unresolved questions, future challenges, and their possible solutions on this topic are presented.
引用
收藏
页码:8378 / 8381
页数:4
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