Molecular structure of an indium(III) iodide-tris(4-methylpyridine) adduct

被引：15

作者：

Brown, MA

Tuck, DG

机构：

[1] Dept. of Chemistry and Biochemistry, University of Windsor, Windsor

来源：

INORGANICA CHIMICA ACTA | 1996年 / 247卷 / 01期

关键词：

indium complexes; iodo complexes; crystal structures;

D O I：

10.1016/0020-1693(95)04951-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The six-coordinate adduct InI3(pic)(3) (pic-4-methylpyridine) has been prepared, and studied by X-ray crystallography. The crystals are monoclinic, space group P2(1)/n, with a=11.430(3), b=13.951(3), c=15.333(2) Angstrom, beta=96.913(15)degrees, Z=4, R=0.062 for 4471 unique reflections. The In-I bond distances are compared with those for a number of related compounds; as with other indium(III) systems, there is a pronounced relationship between r(In-I) and the coordination number at indium.

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页码：135 / 138

页数：4

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