Generation and reactivity of singlet oxygen within zeolites: Remarkable control of hydroperoxidation of alkenes

被引：60

作者：

Robbins, RJ ^{[1
]}

Ramamurthy, V ^{[1
]}

机构：

[1] TULANE UNIV,DEPT CHEM,NEW ORLEANS,LA 70118

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 11期

关键词：

D O I：

10.1039/a700977a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly selective oxidation of alkenes included within a Y zeolite is achieved by generating singlet oxygen via excitation of a monomeric dye exchanged within a zeolite; conformational control brought forth by the medium is suggested to be responsible for the observed remarkable selectivity.

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收藏

页码：1071 / 1072

页数：2

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