Polyelectrolyte theory

被引:151
作者
Holm, C
Joanny, JF
Kremer, K
Netz, RR
Reineker, P
Seidel, C
Vilgis, TA
Winkler, RG
机构
[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
[2] Inst Curie, Sect Rech, F-75248 Paris 05, France
[3] Max Planck Inst Colloids & Interfaces, D-14476 Golm, Germany
[4] Univ Ulm, Theoret Phys Abt, D-89069 Ulm, Germany
[5] Forschungszentrum Julich, Inst Festkorperforsch, D-52425 Julich, Germany
[6] Ludwig Maximilians Univ Munchen, Sekt Phys, D-80333 Munich, Germany
来源
POLYELECTROLYTES WITH DEFINED MOLECULAR ARCHITECTURE II | 2004年 / 166卷
关键词
polyelectrolytes; Poisson-Boltzmann theory; density functional theory; integral equations; scaling theory; annealed polyelectrolytes; computer Simulations;
D O I
10.1007/b11349
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this chapter we review recent advances which have been achieved in the theoretical description and understanding of polyelectrolyte solutions. We will discuss an improved density functional approach to go beyond mean-field theory for the cell model and an integral equation approach to describe stiff and flexible polyelectrolytes in good solvents and compare some of the results to computer simulations. Then we review some recent theoretical and numerical advances in the theory of poor solvent polyelectrolytes. At the end we show how to describe annealed polyelectrolytes in the bulk and discuss their adsorption properties.
引用
收藏
页码:67 / 111
页数:45
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