Polyelectrolyte theory

被引：151

作者：

Holm, C

Joanny, JF

Kremer, K

Netz, RR

Reineker, P

Seidel, C

Vilgis, TA

Winkler, RG

机构：

[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany

[2] Inst Curie, Sect Rech, F-75248 Paris 05, France

[3] Max Planck Inst Colloids & Interfaces, D-14476 Golm, Germany

[4] Univ Ulm, Theoret Phys Abt, D-89069 Ulm, Germany

[5] Forschungszentrum Julich, Inst Festkorperforsch, D-52425 Julich, Germany

[6] Ludwig Maximilians Univ Munchen, Sekt Phys, D-80333 Munich, Germany

来源：

POLYELECTROLYTES WITH DEFINED MOLECULAR ARCHITECTURE II | 2004年 / 166卷

关键词：

polyelectrolytes; Poisson-Boltzmann theory; density functional theory; integral equations; scaling theory; annealed polyelectrolytes; computer Simulations;

D O I：

10.1007/b11349

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In this chapter we review recent advances which have been achieved in the theoretical description and understanding of polyelectrolyte solutions. We will discuss an improved density functional approach to go beyond mean-field theory for the cell model and an integral equation approach to describe stiff and flexible polyelectrolytes in good solvents and compare some of the results to computer simulations. Then we review some recent theoretical and numerical advances in the theory of poor solvent polyelectrolytes. At the end we show how to describe annealed polyelectrolytes in the bulk and discuss their adsorption properties.

引用

页码：67 / 111

页数：45

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