Application of H-1-NOESY NMR spectroscopy to the investigation of ion pair solution structures of organometallic complexes by the detection of interionic contacts

被引：56

作者：

Bellachioma, G ^{[1
]}

Cardaci, G ^{[1
]}

Macchioni, A ^{[1
]}

Reichenbach, G ^{[1
]}

Terenzi, S ^{[1
]}

机构：

[1] UNIV PERUGIA,DIPARTIMENTO CHIM,I-06100 PERUGIA,ITALY

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 21期

关键词：

D O I：

10.1021/om9605645

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The interionic solution structures of trans-[Ru(PMe(3))(2)(CO)(COMe)(pz(2)-CH2)]BPh(4) and trans -[Ru-(PMe(3))(2)(CO)(COMe)(eta(2)-pz(3)-CH)]BPh(4) have been ''directly'' investigated by the detection of interionic contacts in H-1-NOESY NMR spectra between the protons of the organometallic fragments and those of the counterion. BPh(4)(-). A comparison with the solid-state structures obtained by single-crystal X-ray studies has been made.

引用

页码：4349 / 4351

页数：3

共 29 条

[1] 2-DIMENSIONAL H-1 NOESY OF PD(II) PI-ALLYL COMPLEXES - THE CONCEPT OF REPORTER LIGANDS AND THE MOLECULAR-STRUCTURE OF [PD(ETA-3-CH2CCHCH2CH2CH2)(BIQUINOLINE)]CF3SO3
ALBINATI, A
AMMANN, C
PREGOSIN, PS
RUEGGER, H
[J]. ORGANOMETALLICS, 1990, 9 (06) : 1826 - 1833
[2] [Anonymous], 1989, NUCL OVERHAUSER EFFE, DOI DOI 10.1002/MRC.1260280819
[3] THE MECHANISM OF DIRECTED 2ND LITHIATIONS - DETECTION OF SHORT PROTON-LITHIUM SEPARATIONS BY 6LI-1H HOESY
BAUER, W
CLARK, T
SCHLEYER, PV
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (04) : 970 - 977
[4] STRUCTURE OF 2-LITHIOPHENYL TERT-BUTYL THIOETHER IN SOLUTION AND IN THE SOLID-STATE - DETECTION OF AGOSTIC LI-H INTERACTIONS BY NMR-SPECTROSCOPY
BAUER, W
KLUSENER, PAA
HARDER, S
KANTERS, JA
DUISENBERG, AJM
BRANDSMA, L
SCHLEYER, PV
[J]. ORGANOMETALLICS, 1988, 7 (02) : 552 - 555
[5] 2-LITHIO-1-PHENYLPYRROLE - X-RAY STRUCTURE-ANALYSIS AND LI-6-H-1 2D HETERONUCLEAR OVERHAUSER NMR-SPECTROSCOPY (2D HOESY)
BAUER, W
MULLER, G
PI, R
SCHLEYER, PV
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (12): : 1103 - 1104
[6] THE REACTION OF N-BUTYLLITHIUM WITH DIPHENYLACETYLENE - STRUCTURE ELUCIDATION OF THE MONOLITHIO AND DILITHIO PRODUCT BY 1-DIMENSIONAL AND TWO-DIMENSIONAL NMR-SPECTROSCOPY, X-RAY-ANALYSIS, AND MNDO CALCULATIONS - AGOSTIC ACTIVATION BY LITHIUM
BAUER, W
FEIGEL, M
MULLER, G
SCHLEYER, PV
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (18) : 6033 - 6046
[7] PRACTICAL ASPECTS OF TWO-DIMENSIONAL TRANSVERSE NOE SPECTROSCOPY
BAX, A
DAVIS, DG
[J]. JOURNAL OF MAGNETIC RESONANCE, 1985, 63 (01) : 207 - 213
[8] OXIDATIVE ADDITION OF METHYL-IODIDE TO MONOSUBSTITUTED AND DISUBSTITUTED-DERIVATIVES OF RUTHENIUM PENTACARBONYL - PREPARATION OF NEUTRAL AND IONIC COMPLEXES OF RUTHENIUM
BELLACHIOMA, G
CARDACI, G
MACCHIONI, A
MADAMI, A
[J]. INORGANIC CHEMISTRY, 1993, 32 (05) : 554 - 560
[9] MECHANISM OF ISOCYANIDE INSERTION INTO THE METHYL-IRON BOND OF [FE(CO)2L2(CNR)CH3]BPH4
BELLACHIOMA, G
CARDACI, G
MACCHIONI, A
REICHENBACH, G
[J]. INORGANIC CHEMISTRY, 1992, 31 (01) : 63 - 66
[10] DETERMINATION OF THE NUCLEAR-MAGNETIC-RESONANCE SOLUTION STRUCTURE OF AN ANTENNAPEDIA HOMEODOMAIN-DNA COMPLEX
BILLETER, M
QIAN, YQ
OTTING, G
MULLER, M
GEHRING, W
WUTHRICH, K
[J]. JOURNAL OF MOLECULAR BIOLOGY, 1993, 234 (04) : 1084 - 1094

← 1 2 3 →