Adsorption thermodynamics of Methylene Blue onto bentonite

被引:265
作者
Hong, Song [2 ]
Wen, Cheng [2 ]
He, Jing [2 ]
Gan, Fuxing [2 ]
Ho, Yuh-Shan [1 ,3 ]
机构
[1] Asia Univ, Dept Biotechnol, Coll Hlth Sci, Taichung 41354, Taiwan
[2] Wuhan Univ, Sch Resource & Environm Sci, Wuhan 430079, Peoples R China
[3] China Med Univ, Coll Life Sci, Dept Biol Sci & Technol, Taichung 40402, Taiwan
关键词
Sorption; Thermodynamics; Trial-and-error method; Temperature; Bentonite; ADSORBED SOLUTION THEORY; AQUEOUS-SOLUTION; TREE FERN; SORPTION ISOTHERM; METAL-IONS; BASIC DYE; KINETICS; REMOVAL; COPPER; LEAD;
D O I
10.1016/j.jhazmat.2009.01.014
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The effect of temperature on the equilibrium adsorption of Methylene Blue dye from aqueous solution using bentonite was investigated. The equilibrium adsorption data were analyzed using three widely applied isotherms: Langmuir, Freundlich, and Redlich-Peterson. A non-linear method was used for comparing the best fit of the isotherms. Best fit was found to be Redlich-Peterson isotherm. Thermodynamic parameters, such as Delta G degrees, Delta H degrees, and Delta S degrees, were calculated using adsorption equilibrium constant obtained from the Langmuir isotherm. Results suggested that the Methylene Blue adsorption on bentonite was a spontaneous and endothermic process. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:630 / 633
页数:4
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