Microemulsion-assisted synthesis of catalysts based on aluminiurn and magnesium phosphates

被引:4
作者
Aramendía, MA [1 ]
Borau, V [1 ]
Jiménez, C [1 ]
Marinas, JM [1 ]
Romero, FJ [1 ]
Urbano, FJ [1 ]
机构
[1] Univ Cordoba, Dept Organ Chem, E-14014 Cordoba, Spain
关键词
microemulsions; magnesium phosphates; aluminium phosphates; heterogeneous catalysis; isopropyl alcohol;
D O I
10.1016/S1381-1169(01)00470-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Various materials consisting of magnesium (mMgPO-1 and mMgPO-2) or aluminium phosphates (mAlPO-1 and mAlPO-2) were synthesized from microemulsions and characterized in structural terms using X-ray diffraction (XRD), energy dispersive X-ray analysis (EDAX), thermal analysis, and solid-state P-31 and Al-27 NMR spectroscopies. The morphology of the solids was examined by scanning electron microscopy (SEM) and transmission electron microscopy (TEM), and their surfaces properties were determined from N-2 adsorption-desorption isotherms. The new materials thus prepared are structurally and compositionally similar to solids obtained by precipitation from solutions; their specific surface areas, however, are substantially greater and their pore size distribution more narrow. The catalytic activity of the materials in the dehydration-dehydrogenation of isopropyl alcohol was found to be similar to or greater than that of catalysts obtained by precipitation from aqueous solutions. The magnesium orthophosphates yielded acetone (the major product) and propene from 2-propanol; the aluminium orthophosphates, which possess dehydrating activity only, yielded propene alone. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:35 / 46
页数:12
相关论文
共 37 条
[1]  
ALBERTI G, 1996, SOLID STATE SUPRAMOL, P425
[2]  
[Anonymous], TOPICS PHOSPHORUS CH
[3]   Influence of the structure and composition of magnesium phosphate catalysts on the transformation of 2-hexanol [J].
Aramendía, MA ;
Borau, V ;
Jiménez, C ;
Marinas, JM ;
Romero, FJ ;
Urbano, FJ .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 182 (01) :25-34
[4]   Synthesis, characterization, and catalytic uses of Mg3(PO4)2/MgO systems [J].
Aramendía, MA ;
Borau, V ;
Jiménez, C ;
Marinas, JM ;
Romero, FJ .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1999, 219 (01) :201-209
[5]  
Aramendía MA, 1999, APPL CATAL A-GEN, V183, P73
[6]   Synthesis and characterization of basic catalysts based on sodium-magnesium mixed phosphates and their use in the conversion of 2-hexanol [J].
Aramendía, MA ;
Borau, V ;
Jiménez, C ;
Marinas, JM ;
Romero, FJ ;
Urbano, FJ .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2001, 240 (01) :237-244
[7]   The Meerwein-Ponndorf-Verley-Oppenauer reaction between 2-hexanol and cyclohexanone on magnesium phosphates [J].
Aramendía, MA ;
Borau, V ;
Jiménez, C ;
Marinas, JM ;
Romero, FJ .
CATALYSIS LETTERS, 1999, 58 (01) :53-58
[8]   Vapour-phase reaction of acetophenone with methanol or dimethyl carbonate on magnesium oxide and magnesium phosphates [J].
Aramendía, MA ;
Borau, V ;
Jiménez, C ;
Marinas, JM ;
Romero, FJ .
JOURNAL OF CATALYSIS, 1999, 183 (01) :119-127
[9]   MODIFICATION OF THE ACTIVITY OF MG-3(PO4)(2) IN THE GAS-PHASE CONVERSION OF CYCLOHEXANOL BY ADDITION OF SODIUM-CARBONATE [J].
ARAMENDIA, MA ;
BORAU, V ;
JIMENEZ, C ;
MARINAS, JM ;
ROMERO, FJ ;
NAVIO, JA ;
BARRIOS, J .
JOURNAL OF CATALYSIS, 1995, 157 (01) :97-108
[10]   XRD and solid-state NMR study of magnesium oxide magnesium orthophosphate systems [J].
Aramendia, MA ;
Borau, V ;
Jimenez, C ;
Marinas, JM ;
Romero, FJ ;
Ruiz, JR .
JOURNAL OF SOLID STATE CHEMISTRY, 1998, 135 (01) :96-102