Photoinduced hydrogen evolution with lysine-linked viologen and hydrogenase

被引：10

作者：

Asakura, N ^{[1
]}

Miyaji, A ^{[1
]}

Kamachi, T ^{[1
]}

Okura, I ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Bioengn, Yokohama, Kanagawa 2268501, Japan

来源：

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2002年 / 6卷 / 01期

关键词：

porphyrin; viologen; lysine; photoinduced hydrogen evolution; hydrogenase;

D O I：

10.1142/S1088424602000051

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Lysine-linked viologen was prepared as a substrate for the hydrogenase. By using reduced lysine-linked viologen (LysV(+circle)), the hydrogenase-LysV(+circle) complex was formed efficiently, leading to effective hydrogen evolution compared with methyl viologen. Lysine-linked viologen as an electron carrier was applied for the photoinduced hydrogen evolution system containing hydrogenase, Tetrakis(4-carboxyphenyl)porphyrin (TCPP) as a photosensitizer, and a sacrificial electron donor for TCPP. In this system, effective photoinduced hydrogen evolution was observed. Copyright (C) 2002 Society of Porphyrins & Phthalocyanines.

引用

页码：26 / 32

页数：7

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