High-throughput synthesis and screening of ternary metal alloys for electrocatalysis

被引：60

作者：

Guerin, Samuel ^{[1
]}

Hayden, Brian E. ^{[1
]}

Lee, Christopher E. ^{[1
]}

Mormiche, Claire ^{[1
]}

Russell, Andrea E. ^{[1
]}

机构：

[1] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2006年 / 110卷 / 29期

关键词：

D O I：

10.1021/jp061967d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report the application of a new method for the high-throughput synthesis and screening of thin film materials and its application to the discovery of electrocatalysts. Results are presented for the PtPdAu ternary alloy system with respect to activity for oxygen reduction. The results reveal an enhancement in activity for a range of PtPd alloy compositions over either of the pure elements. An optimum composition range of ternary alloys with significant activity was also identified. A correlation was also investigated between the surface reduction potential and the activity for oxygen reduction in both binary and ternary alloys. The results demonstrate the potential of the methodology for the discovery and optimization of electrocatalysts for a wide range of applications.

引用

页码：14355 / 14362

页数：8

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