Implications of heat treatment on the properties of a magnetic iron oxide-titanium dioxide photocatalyst

Magnetic iron oxide-titania photocatalysts (Fe(3)O(4)-TiO(2)) were prepared using a coating technique in which the photoactive titanium dioxide was deposited onto the surface of a magnetic iron oxide core. These particles had a core-shell structure. The prepared particles were heat treated at high temperature in order to transform the amorphous titanium dioxide into a photoactive crystalline phase. The heat treatment temperature and duration were varied, and the correlation between the heat treatment and the observed photoactivities was investigated. An increase in the applied heat treatment, either by increasing the temperature or increasing the heat treatment duration, led to a decrease in the activities of the catalyst particles. A decrease in surface area due to sintering, along with the diffusion of Fe ions into the titanium dioxide coating are seen as contributing factors to the decline in photoactivity which accompanied an increase in the heat treatment. Differential scanning calorimetry analysis (DSC) results confirmed that the presence of the iron oxide core did not have an effect on the phase transformation of titania under the experimental conditions investigated. In this study we also present surface charge measurements which show that the surface of the particles became more positive as the heat treatment was increased. This is an indication of changing surface properties as heat treatment is applied. For single-phase TiO(2) Powders, this is postulated to be due to a decrease in the surface hydroxyl (OH) groups and/or residual organics (OR) groups. For the Fe(3)O(4)-TiO(2) powders, in addition to the loss of OH and OR groups, the diffusion of the Fe into the titania shell is postulated to also play a role in the changing surface properties with applied heat treatment. Experiments aimed at reducing the duration of the heat treatment revealed that a heat treatment duration of 20 min at 450 degreesC was sufficient to transform amorphous titanium dioxide into a photoactive crystalline phase. This does not only minimise loss of surface hydroxyl groups but it also has the potential to limit the oxidation of the magnetic core, which occurs due to the porosity of the coating. This has practical implications in terms of separating the magnetic particles from the treated waste waters under the application of an external magnetic field. It also presents an opportunity to produce photoactive composite particles while limiting the interactions between the core and the shell during the heat treatment. (C) 2002 Elsevier Science B.V. All rights reserved.