Synthesis and characterization of a saddle-shaped nickel-carbene complex derived from an imidazolium-linked meta-cyclophane

被引：86

作者：

Baker, MV ^{[1
]}

Skelton, BW ^{[1
]}

White, AH ^{[1
]}

Williams, CC ^{[1
]}

机构：

[1] Univ Western Australia, Dept Chem, Crawley, WA 6009, Australia

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 13期

关键词：

D O I：

10.1021/om011031l

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel nickel complex in which the nickel center is bonded to two pyridine units and two heterocyclic carbene units in an imidazolium linked meta-cyclophane skeleton has been synthesized and structurally characterized. Both the parent imidazolium-linked cyclophane and the nickel complex undergo H/D exchange reactions in D2O solutions.

引用

页码：2674 / 2678

页数：5

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