Catalytic olefin hydrogenation using N-heterocyclic carbene-phosphine complexes of iridium

被引：139

作者：

Vázquez-Serrano, LD ^{[1
]}

Owens, BT ^{[1
]}

Buriak, JM ^{[1
]}

机构：

[1] Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 21期

关键词：

D O I：

10.1039/b208403a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

N-heterocyclic carbene-phosphine complexes of iridium have been synthesized and examined for their performance in the catalytic homogeneous hydrogenation of a range of olefins; the reaction was further explored using para-hydrogen induced polarization (PHIP) H-1 NMR.

引用

页码：2518 / 2519

页数：2

共 21 条

[1] ELECTRONIC STABILIZATION OF NUCLEOPHILIC CARBENES [J].

ARDUENGO, AJ ;

DIAS, HVR ;

HARLOW, RL ;

KLINE, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (14) :5530-5534

[2]

ARDUENGO AJ, 2002, STREM CHEM, V19, P2

[3] ORTHOHYDROGEN AND PARAHYDROGEN INDUCED NUCLEAR-SPIN POLARIZATION [J].

BARGON, J ;

KANDELS, J ;

WOELK, K .

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 1993, 180 :65-93

[4]

BHADUR S, 1994, HOMOGENEOUS CATALYSI

[5] First chelated chiral N-Heterocyclic bis-carbene complexes [J].

Clyne, DS ;

Jin, J ;

Genest, E ;

Gallucci, JC ;

RajanBabu, TV .

ORGANIC LETTERS, 2000, 2 (08) :1125-1128

[6] IRIDIUM COMPOUNDS IN CATALYSIS [J].

CRABTREE, R .

ACCOUNTS OF CHEMICAL RESEARCH, 1979, 12 (09) :331-338

[7] CATIONIC IRIDIUM DIOLEFIN COMPLEXES AS ALKENE HYDROGENATION CATALYSTS AND ISOLATION OF SOME RELATED HYDRIDO COMPLEXES [J].

CRABTREE, RH ;

FELKIN, H ;

MORRIS, GE .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 141 (02) :205-215

[8] PARAHYDROGEN-INDUCED POLARIZATION - A NEW SPIN ON REACTIONS WITH H2 [J].

EISENBERG, R .

ACCOUNTS OF CHEMICAL RESEARCH, 1991, 24 (04) :110-116

[9] N-heterocyclic carbenes [J].

Herrmann, WA ;

Kocher, C .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (20) :2162-2187

[10] N-heterocyclic carbenes.: 20.: Homoleptic chelating N-heterocyclic carbene complexes of palladium and nickel [J].

Herrmann, WA ;

Schwarz, J ;

Gardiner, MG ;

Spiegler, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 575 (01) :80-86

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