Novel flavonol glycoside, 7-O-methyl mearnsitrin, from Sageretia theezans and its antioxidant effect

被引:80
作者
Chung, SK [1 ]
Kim, YC
Takaya, Y
Terashima, K
Niwa, M
机构
[1] Kyungpook Natl Univ, Dept Food Sci & Technol, Taegu 702701, South Korea
[2] Korea Food Res Inst, Songnam 463746, South Korea
[3] Meijo Univ, Fac Pharm, Tempa Ku, Nagoya, Aichi 4688503, Japan
关键词
flavonol glycosides; 7-O-methylmearnsitrin; Sageretia theezans; ESR; LDL oxidation;
D O I
10.1021/jf049526j
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
A novel flavonol glycoside, 7-O-methylmearnsitrin (7,4'-O-dimethylmyricetin 3-O-alpha-L-rhamnopyranoside), and myricetrin, kaempferol 3-O-alpha-L-rhamnopyranoside, europetin 3-O-alpha-L-rhamnoside, and 7-O- methyl quercetin 3-O-alpha-L-rhamnopyranoside were isolated from the leaves of Sageretia theezans, and their chemical structures were identified by spectroscopic analyses including two-dimensional NMR (HSQC, HMBC). Whereas myricetrin, europetin 3-O-alpha-L-rhamnoside, and 7-O-methylquercetin 3-O-alpha-L-rhamnopyranoside showed stronger activities than ascorbic acid and alpha-tocopherol, 7-O- methylmearnsitrin showed very weak antioxidant activities by ESR and LDL oxidation inhibition tests.
引用
收藏
页码:4664 / 4668
页数:5
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