IM-19: a new flexible microporous gallium based-MOF framework with pressure- and temperature-dependent openings

被引：57

作者：

Chaplais, Gerald ^{[3
]}

Simon-Masseron, Angelique ^{[3
]}

Porcher, Florence ^{[1
,2
,4
]}

Lecomte, Claude ^{[4
]}

Bazer-Bachi, Delphine ^{[5
]}

Bats, Nicolas ^{[5
]}

Patarina, Joel ^{[3
]}

机构：

[1] CEA, IRAMIS, Leon Brillouin Lab, F-91191 Gif Sur Yvette, France

[2] CEA, CNRS, LLB, UMR 12, F-91191 Gif Sur Yvette, France

[3] Univ Haute Alsace, CNRS, Equipe Mat Porosite Controlee MPC, IS2M,ENSCMu,LCR 7228, F-68093 Mulhouse, France

[4] Univ Nancy 1, CNRS, CRM2, UMR 7036, F-54506 Vandoeuvre Les Nancy, France

[5] IFP Lyon, F-69360 Solaize, France

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2009年 / 11卷 / 26期

关键词：

METAL-ORGANIC FRAMEWORKS; SOLID-STATE NMR; CRYSTAL-STRUCTURES; HYDROGEN ADSORPTION; LAMELLAR GALLIUM; GIANT PORES; GA-71; PHOSPHONATES; MIL-53; ROUTE;

D O I：

10.1039/b822163d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Five metal-organic frameworks (MOFs) based on the same three-dimensional gallium terephthalate network (IM-19) are described, and an incommensurate structure (for the as-synthesized form) as well as two remarkable guest-free polymorphs (open and closed) are highlighted.

引用

页码：5241 / 5245

页数：5

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