Silver-promoted reactions of bicyclo[3.2.1]octadiene derivatives

被引：20

作者：

Orugunty, RS ^{[1
]}

Wright, DL ^{[1
]}

Battiste, MA ^{[1
]}

Abboud, KA ^{[1
]}

机构：

[1] Univ Florida, Dept Chem, Gainesville, FL 32606 USA

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 12期

关键词：

D O I：

10.1021/ol0258740

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHIC] Highly substituted bicyclo[3.2.1]octadiene building blocks are easily prepared from tetrachloro- or tetrabromocyclopropene through reaction with cyclic dienes. These polyhalogenated derivatives can serve as precursors to a variety of functionalized bridged bicyclic compounds. Herein, we report on the generation and reaction of electrophilic species with silver ion.

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页码：1997 / 2000

页数：4

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