Novel metallacycle complexes from bis(oxazolinyl)pyridine-rhodium(I) species and diynes

被引：37

作者：

Nishiyama, H ^{[1
]}

Niwa, E ^{[1
]}

Inoue, T ^{[1
]}

Ishima, Y ^{[1
]}

Aoki, K ^{[1
]}

机构：

[1] Toyohashi Univ Technol, Sch Math Sci, Toyohashi, Aichi 4418580, Japan

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 13期

关键词：

D O I：

10.1021/om0202221

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Rh(coe)(2)Cl](2) (coe = cis-cyclooctene), bis(oxazolinyl)pyridine (pybox), and diynes (O(CH(2)Cequivalent toCCO(2)Me)(2) and PhCequivalent toCCH(2)OCH(2)Cequivalent toCCO(2)Me) gave new types of metallacycle complexes, which were analyzed by X-ray crystallography and showed catalytic activity for cycloaddition of diynes and several alkynes.

引用

页码：2572 / 2574

页数：3

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