Polyhydroxycarbosilanes of dendritic structure

被引：21

作者：

Getmanova, EV

Chenskaya, TB

Gorbatsevich, OB

Rebrov, EA

Vasilenko, NG

Muzafarov, AM

机构：

来源：

REACTIVE & FUNCTIONAL POLYMERS | 1997年 / 33卷 / 2-3期

关键词：

dendrimers; hyperbranched polymers; hydroxylated polycarbosilanes; H bonds;

D O I：

10.1016/S1381-5148(97)00066-7

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Synthesis of a versatile hydroxysilylation agent and its use in the preparation of hydroxy derivatives of a poly(allylcarbosilane) dendrimer and hyperbranched polymer are reported. In a first approximation, the bulk properties of synthesized hydroxy polymers are found to essentially identical. Infrared spectroscopy provides evidence for the build-up of a complicated H-bond network in these polymers. Spectroscopic study of the hydroxyl groups can gain a deeper insight into the properties of branched dendrite-core macromolecules.

引用

页码：289 / 297

页数：9

共 13 条

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