Efficient and selective Al-catalyzed alcohol oxidation via Oppenauer chemistry

被引：73

作者：

Graves, Christopher R.

Zeng, Bi-Shun

Nguyen, SonBinh T.

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] Northwestern Univ, Inst Environm Catalysis, Evanston, IL 60208 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 39期

关键词：

D O I：

10.1021/ja063842s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly active and selective Al-based catalytic Oppenauer (O) oxidation is reported. Quantitative and selective oxidations of a variety of benzylic, propargylic, allylic, and aliphatic primary and secondary alcohols were achieved using nitrobenzaldehyde derivatives as the oxidant and simple aluminum compounds as precatalysts. Copyright © 2006 American Chemical Society.

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页码：12596 / 12597

页数：2

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