Ruthenium cluster carbonyls containing ligands derived from ferrocenylalkynes

被引：27

作者：

Bruce, MI ^{[1
]}

Skelton, BW

White, AH

Zaitseva, NN

机构：

[1] Univ Western Australia, Dept Chem, Crawley, WA 6009, Australia

[2] Univ Adelaide, Dept Chem, Adelaide, SA 5005, Australia

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 650卷 / 1-2期

基金：

澳大利亚研究理事会;

关键词：

ruthenium; ferrocene; alkyne; diyne; X-ray structures;

D O I：

10.1016/S0022-328X(02)01220-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of FcC=CH (a), HCequivalent toCCequivalent toCFc (b) and FcCequivalent toCCequivalent toCFc (c) with Ru-3(CO)(10)(NCMe)(2) (all) and Ru-3(mu-dppm)(CO)(10) (b and c only) are described. Among the products, the complexes Ru-3(mu(3)-RC2R')(mu-CO)(CO)(9) (R = H, R'= Fc 1, Cequivalent toCFc 2; R = R'= Fc 5), Ru-3(mu-H)(mu(3)-C(2)Cequivalent toCFe)(mu-dppm)(CO)(7) 3, Ru-3(mu(3)-FcCCequivalent toCFc)(mu-dppm)(mu-CO)(CO)(7) 6 and Ru-3{mu(3)-C(4)Fc(2)(Cequivalent toCFc), (mu-dppm)(mu-CO)(CO)(5) 7 were characterised, including single-crystal structure determinations for 1, 3, 5 and 7; that of 7 did not differ significantly from an earlier study of a mixed CH2Cl2-C6H6 solvate. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：188 / 197

页数：10

共 31 条

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