Synthesis, x-ray structure, and characterization of Ag(hfa)•tetraglyme [hfa = hexafluoroacetylacetonate]:: A novel adduct for the fabrication of metallic silver based films via in situ self reduction

被引：26

作者：

Fragalà, ME

Malandrino, G

Puglisi, O

Benelli, C

机构：

[1] Univ Catania, Dipartimento Sci Chim, I-95100 Catania, Italy

[2] Univ Florence, Dipartimento Chim, I-50144 Florence, Italy

来源：

CHEMISTRY OF MATERIALS | 2000年 / 12卷 / 02期

关键词：

D O I：

10.1021/cm9911215

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new adduct, Ag(hfa).tetraglyme has been synthesized through the reaction of silver oxide, hexafluoroacetylacetone, and polyether in dichloromethane. The solubility and thermal behavior indicate that this adduct is a promising silver precursor for spin coating of silver-containing films. The present synthetic strategy opens a new route to an interesting generation of silver complexes, allowing the production of silver nanocomposites; in which the cluster dimensions can be tailored by the presence of an insulating medium.

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页码：290 / +

页数：5

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