A review of plutonium(IV) selective ligands

被引：42

作者：

OBoyle, NC

Nicholson, GP

Piper, TJ

Taylor, DM

Williams, DR

Williams, G

机构：

[1] UNIV WALES COLL CARDIFF,DEPT CHEM,CARDIFF CF1 3TB,S GLAM,WALES

[2] AWE PLC,ANALYT CHEM BRANCH,READING RG7 4PR,BERKS,ENGLAND

来源：

APPLIED RADIATION AND ISOTOPES | 1997年 / 48卷 / 02期

关键词：

D O I：

10.1016/S0969-8043(96)00128-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review compares 40 chelating ligands of differing denticity and basicity for the recovery of Pu from process waste streams. These ligands have been shown to form stable Pu(IV) complexes and to be selective for the Pu(IV) ion. Three plutonophiles identified as potentially cost-effective chelators for waste treatment are the siderophore analogue DFO-HOPO, the novel actinide-chelating diphonix resin and the amide substituted N-macrocycle TCM-12aneN(4). Possible means of isolating Pu on related chelating resins are explored. Copyright (C) 1997 Elsevier Science Ltd

引用

页码：183 / 200

页数：18

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