Stereospecific anionic polymerization of novel α-substituted acrylates bearing aromatic heterocycles

被引：3

作者：

Habaue, S ^{[1
]}

Baraki, H ^{[1
]}

Shibagaki, T ^{[1
]}

Okamoto, Y ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, Chikusa Ku, Nagoya, Aichi 4648603, Japan

来源：

POLYMER JOURNAL | 2000年 / 32卷 / 02期

关键词：

stereospecific polymerization; anionic polymerization; alpha-substituted acrylate; aromatic heterocycle; isotactic polymer; lithium reagent;

D O I：

10.1295/polymj.32.173

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Three novel α-substituted acrylates bearing aromatic heterocycles were anionically polymerized to produce vinyl polymers. The bulkiness and coordination ability of the polar substituents of the growing polymer and monomers to the counter-cations Li+ and MgBr+ greatly affected the streoregularity and polymerizability of the polymers.

引用

页码：173 / 177

页数：5

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