Chain transfer to polymer: A convenient route to macromonomers

被引：154

作者：

Chiefari, J ^{[1
]}

Jeffery, J ^{[1
]}

Mayadunne, RTA ^{[1
]}

Moad, G ^{[1
]}

Rizzardo, E ^{[1
]}

Thang, SH ^{[1
]}

机构：

[1] CSIRO, Mol Sci, Clayton, Vic 3169, Australia

来源：

MACROMOLECULES | 1999年 / 32卷 / 22期

关键词：

D O I：

10.1021/ma990488s

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new process to prepare polyacrylate and polystyrene monomers is described. The method is clean, simple, and economical and involves heating a mixture of either acrylate or styrene monomer in an appropriate solvent with an azo or peroxy initiator at elevated temperatures.

引用

页码：7700 / 7702

页数：3

共 25 条

[1] Chain transfer to polymer in free-radical solution polymerization of n-butyl acrylate studied by NMR spectroscopy
Ahmad, NM
Heatley, F
Lovell, PA
[J]. MACROMOLECULES, 1998, 31 (09) : 2822 - 2827
[2] BEUERMANN S, 1996, MACROMOLECULES, V31, P2822
[3] COBALOXIME AS A CATALYTIC CHAIN TRANSFER AGENT
BURCZYK, AF
ODRISCOLL, KF
REMPEL, GL
[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1984, 22 (11) : 3255 - 3262
[4] COPOLYMERIZATION OF OMEGA-UNSATURATED OLIGO(METHYL METHACRYLATE) - NEW MACROMONOMERS
CACIOLI, P
HAWTHORNE, DG
LASLETT, RL
RIZZARDO, E
SOLOMON, DH
[J]. JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1986, A23 (07): : 839 - 852
[5] Chiefari J., 1998, WO Pat, Patent No. 9847927
[6] CHIEFARI J, IN PRESS MACROMOLECU
[7] DARMON MJ, 1992, Patent No. 5362826
[8] DAVIS TP, 1994, J MACROMOL SCI R M C, VC34, P243
[9] DAVIS TP, 1995, TRENDS POLYM SCI, V3, P365
[10] COPOLYMERIZATION PROPAGATION KINETICS OF STYRENE WITH ALKYL ACRYLATES
DAVIS, TP
ODRISCOLL, KF
PITON, MC
WINNIK, MA
[J]. POLYMER INTERNATIONAL, 1991, 24 (02) : 65 - 70

← 1 2 3 →