Cationic η1/η2-gold(I) complexes of simple arenes

被引：242

作者：

Herrero-Gomez, Elena ^{[1
]}

Nieto-Oberhuber, Cristina ^{[1
]}

Lopez, Salome ^{[1
]}

Benet-Buchholz, Jordi ^{[1
]}

Echavarren, Antonio M. ^{[1
]}

机构：

[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 33期

关键词：

pi interactions; arene ligands; enynes; gold; phosphanes;

D O I：

10.1002/anie.200601688

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) In close contact: The first gold(I) complexes of simple arenes show a separation between the Au center and the mean aromatic plane of 2.20-2.24 Å, which is much shorter than the related silver(I)-arene bonds. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5455 / 5459

页数：5

共 52 条

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