Reactive milling of graphite with lithium:: Application to lithium batteries

被引：11

作者：

Azaïs, P ^{[1
]}

Duclaux, L ^{[1
]}

Faugère, AM ^{[1
]}

Béguin, F ^{[1
]}

机构：

[1] Univ Orleans, CNRS, Div Mat, Ctr Rech, F-45071 Orleans 2, France

来源：

APPLIED PHYSICS LETTERS | 2002年 / 81卷 / 04期

关键词：

D O I：

10.1063/1.1493236

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

Reactive milling of graphite with lithium has been performed in order to develop bonding between carbon and lithium atoms and thus to prepare insertion compounds with C/Li molar ratios lower than 6 (C/Li=6, 4 and 2). A test of these new compounds as anodes of Li batteries has shown higher reversible capacities than graphite (372 mA h/g), weaker hysteresis, and smaller irreversible capacities than milled graphite under the same conditions. This is explained by the formation of a lithiated surface. (C) 2002 American Institute of Physics.

引用

页码：775 / 777

页数：3

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