Sulfonatocalixarenes: molecular capsule and 'Russian doll' arrays to structures mimicking viral geometry

被引：169

作者：

Dalgarno, Scott J. ^{[1
]}

Atwood, Jerry L.

Raston, Colin L.

机构：

[1] Univ Missouri, Dept Chem, Columbia, MO 65211 USA

[2] Univ Western Australia, Sch Biomed Biomol & Chem Sci, Perth, WA 6909, Australia

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 44期

关键词：

D O I：

10.1039/b606803k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

p-Sulfonatocalix[4,5,6,8] arenes are versatile building blocks, able to assemble into 'molecular capsule' arrays based on two calixarenes, as well as a variety of other structural motifs, with the extended structures dominated by the formation of bilayers. For p-sulfonatocalix[ 4] arene, assembly into nanometre scale spheroids ( of either icosahedral or cuboctahedral geometries) as well as nanotubules ( all of which take on structural features akin to those of viruses) is possible, depending on the guest molecules and lanthanides present in solution.

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页码：4567 / 4574

页数：8

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