[Co(NH3)6]3[Cu4(OH)(CO3)8]•2H2O -: a new carbonato-copper(II) anion stabilized by extensive hydrogen bonding

被引：33

作者：

Abrahams, BF ^{[1
]}

Haywood, MG ^{[1
]}

Robson, R ^{[1
]}

机构：

[1] Univ Melbourne, Sch Chem, Parkville, Vic 3010, Australia

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 08期

关键词：

D O I：

10.1039/b316925a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Addition of Co(NH3)(6)(3+) to aqueous solutions of Cu-II in excess carbonate promotes the assembly of a new highly charged carbonato-copper(II) anion, [Cu-4(OH)(CO3)(8)](9-), which contains an unusual mu(4) hydroxo-bridged square Cu-4 arrangement, stabilised in the crystal by no less than forty hydrogen bonds (< 3 angstrom) to hexammine cations.

引用

页码：938 / 939

页数：2

共 5 条

[1] New tricks for an old dog:: The carbonate ion as a building block for networks including examples of composition [Cu6(CO3)12-{C(NH2)3}8]4- with the sodalite topology
Abrahams, BF
Haywood, MG
Robson, R
Slizys, DA
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (10) : 1112 - 1115
[2] BELL M, 1987, CHEM COMMUN, P1852
[3] CHEMICAL AND PHYSICAL-PROPERTIES OF TRIANGULAR BRIDGED METAL-COMPLEXES
CANNON, RD
WHITE, RP
[J]. PROGRESS IN INORGANIC CHEMISTRY, 1988, 36 : 195 - 298
[4] THE CHEMISTRY OF METAL CARBONATO AND CARBON-DIOXIDE COMPLEXES
PALMER, DA
VANELDIK, R
[J]. CHEMICAL REVIEWS, 1983, 83 (06) : 651 - 731
[5] Sheldrick G. M., 1997, SHELX 97 PROGRAM CRY

← 1 →