Water-assisted fabrication of polyaniline honeycomb structure film

被引:51
作者
Yu, CL
Zhai, J [1 ]
Gao, XF
Wan, MX
Jiang, L
Li, TJ
Li, ZS
机构
[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
[2] Jilin Univ, Changchun 130022, Peoples R China
关键词
D O I
10.1021/jp037719o
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An ordered honeycomb structure of 4-dodecylbenzenesulfonic acid (DBSA)-doped polyaniline (PANI) is fabricated in a humid atmosphere. By controlling both the relative humidity in the atmosphere and the concentration of the conducting polymer, different morphologies of the honeycomb structure can be obtained. The driving force of this procedure is capillary force (self-assembly), and water droplets serve as a template. Furthermore, the honeycomb structure film of PANI-DBSA is proved to be electroactive and exhibits semiconducting properties in the appropriate doping state.
引用
收藏
页码:4586 / 4589
页数:4
相关论文
共 21 条
[1]   Electrochemical syntheses of highly ordered macroporous conducting polymers grown around self-assembled colloidal templates [J].
Bartlett, PN ;
Birkin, PR ;
Ghanem, MA ;
Toh, CS .
JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (03) :849-853
[2]   GROWTH OF BREATH FIGURES [J].
BEYSENS, D ;
KNOBLER, CM .
PHYSICAL REVIEW LETTERS, 1986, 57 (12) :1433-1436
[3]   THE EVOLUTION OF A 2D-CONSTRAINED GROWTH SYSTEM OF DROPLETS - BREATH FIGURES [J].
BRISCOE, BJ ;
GALVIN, KP .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1990, 23 (04) :422-428
[4]   PHOTOASSISTED SCANNING TUNNELING MICROSCOPY AND TUNNELING SPECTROSCOPY OF N-TYPE TUNGSTEN DISELENIDE (N-WSE2) SINGLE-CRYSTALS [J].
FAN, FRF ;
BARD, AJ .
JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (07) :1431-1436
[5]   Self-assembly of ordered microporous materials from rod-coil block copolymers [J].
Jenekhe, SA ;
Chen, XL .
SCIENCE, 1999, 283 (5400) :372-375
[6]   Synthesis of nanoporous silica with new pore morphologies by templating the assemblies of ionic block copolymers [J].
Kramer, E ;
Forster, S ;
Goltner, C ;
Antonietti, M .
LANGMUIR, 1998, 14 (08) :2027-2031
[7]   ORDERED MESOPOROUS MOLECULAR-SIEVES SYNTHESIZED BY A LIQUID-CRYSTAL TEMPLATE MECHANISM [J].
KRESGE, CT ;
LEONOWICZ, ME ;
ROTH, WJ ;
VARTULI, JC ;
BECK, JS .
NATURE, 1992, 359 (6397) :710-712
[8]  
LI YM, 1998, J FUNCTIONAL POLYM, V11, P337
[9]  
Manz A, 1998, MICROSYSTEM TECHNOLO
[10]   Mesoscopic pattern formation of nanostructured polymer assemblies [J].
Maruyama, N ;
Karthaus, O ;
Ijiro, K ;
Shimomura, M ;
Koito, T ;
Nishimura, S ;
Sawadaishi, T ;
Nishi, N ;
Tokura, S .
SUPRAMOLECULAR SCIENCE, 1998, 5 (3-4) :331-336