Permeability of polymer/clay nanocomposites: A review

被引:810
作者
Choudalakis, G. [1 ]
Gotsis, A. D. [1 ]
机构
[1] Tech Univ Crete, Dept Sci, GR-73100 Hania, Greece
关键词
Gas permeability; Barrier properties; Permeation models; Nano-clay; Nanocomposite; GAS BARRIER PROPERTIES; LAYERED SILICATE NANOCOMPOSITES; CLAY NANOCOMPOSITES; POSITRON-ANNIHILATION; TRANSPORT-PROPERTIES; COATING APPLICATIONS; FREE-VOLUME; DIFFUSION; MONTMORILLONITE; COMPOSITES;
D O I
10.1016/j.eurpolymj.2009.01.027
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
This is a review of the existing studies on the permeability of gas molecules in nanocomposite materials that consist of inorganic platelet-shaped fillers in polymeric matrices. We describe the dominant mechanisms for the transport of small molecules in polymers and polymer nanocomposites, as well as the procedures for the measurement of the permeability and the diffusivity. The emphasis is given on the various models that have been proposed for the prediction of permeability in polymer-clay nanocomposites. The influence of the characteristics of the inorganic particles on the barrier properties of the composite membrane is discussed and tested using the model and the available experimental data. Some aspects on the methods of improving the barrier properties of the nanocomposite are examined and a few applications of these materials as gas barriers are presented. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:967 / 984
页数:18
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