Stable single-layer light-emitting electrochemical cell using 4,7-diphenyl-1,10-phenanthroline-bis(2-phenylpyridine) iridium(III) hexafluorophosphate

被引:182
作者
Bolink, Henk J.
Cappelli, Luca
Coronado, Eugenio
Graetzel, Michael
Orti, Enrique
Costa, Ruben D.
Viruela, Pedro M.
Nazeeruddin, Md. K.
机构
[1] Univ Valencia, Inst Ciencia Mol, ES-46071 Valencia, Spain
[2] Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, CH-1015 Lausanne, Switzerland
关键词
D O I
10.1021/ja066416f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A significant improvement in the stability of a light emitting electrochemical cell was achieved by utilizing a novel iridium(III) complex: 4,7-diphenyl-1,10-phenanthroline-bis(2-phenylpyridine)iridium(III) hexafluorophosphate. The enhanced device stability is correlated by means of DFT studies to be related to a more efficient shielding of the reactive LUMO of the complex. Copyright © 2006 American Chemical Society.
引用
收藏
页码:14786 / 14787
页数:2
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