Metastable-stable phase diagrams in the zirconia-containing systems utilized in solid-oxide fuel cell application

被引:314
作者
Yashima, M
Kakihana, M
Yoshimura, M
机构
[1] Materials and Structures Laboratory, Tokyo Institute of Technology
关键词
solid oxide fuel cell; phase diagrams; Raman spectroscopy;
D O I
10.1016/0167-2738(96)00386-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Metastable-stable phase diagrams of ZrO2-RO(1.5) systems (R=Y, Sc and Er) are reviewed, noting the cation-diffusionless transformations and reasonable diagrams are proposed. A tetragonal phase with an axial ratio of unity is interpreted to appear in the compositional region around 16 mol.% YO1.5.
引用
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页码:1131 / 1149
页数:19
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