Novel palladium(II) complex containing a chelating anionic N-O ligand: Efficient carbonylation catalyst

被引：53

作者：

Jayasree, S ^{[1
]}

Seayad, A ^{[1
]}

Chaudhari, RV ^{[1
]}

机构：

[1] Natl Chem Lab, Homogeneous Catalysis Div, Poon 411008, Maharashtra, India

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 02期

关键词：

D O I：

10.1021/ol9912884

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel palladium(II) complex containing chelating anionic pyridine-2-carboxylato and labile tosylato ligands is a highly efficient catalyst for the carbonylation of organic alcohols and olefins to carboxylic acids/esters. Carbonylation of primary, secondary, and tertiary alcohols as well as linear and functionalized terminal olefins was studied. In all cases remarkable activity and selectivity were observed, The catalyst is stable under reaction conditions even in the absence of excess phosphine ligands.

引用

页码：203 / 206

页数：4

共 26 条

[1] [Anonymous], [No title captured], Patent No. [EP 400892, 400892]
[2] Beller M, 1998, CHEM-EUR J, V4, P935, DOI 10.1002/(SICI)1521-3765(19980515)4:5<935::AID-CHEM935>3.0.CO
[3] 2-#
[4] Gas-liquid-liquid reaction engineering: the Koch synthesis of pivalic acid from iso- and tert-butanol; Reaction kinetics and the effect of a dispersed second-liquid phase
Brilman, DWF
van Swaaij, WPM
Versteeg, GF
[J]. CHEMICAL ENGINEERING SCIENCE, 1999, 54 (21) : 4801 - 4809
[5] CHAUDHARI RV, 1999, Patent No. 3697
[6] Colquhoun H. M., 1991, CARBONYLATION DIRECT
[7] Cornils B., 1996, APPL HOMOGENEOUS CAT, V2
[8] Cornils B., 1996, APPL HOMOGENEOUS CAT, V1
[9] A highly selective water-soluble dicationic palladium catalyst for the biphasic hydroxycarbonylation of alkenes
Goedheijt, MS
Reek, JNH
Kamer, PCJ
van Leeuwen, PWNM
[J]. CHEMICAL COMMUNICATIONS, 1998, (22) : 2431 - 2432
[10] Palladium-catalyzed carbonylation of propargylamines. Selective insertion of carbon monoxide into a carbon-nitrogen bond
Imada, Y
Alper, H
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (20) : 6766 - 6767

← 1 2 3 →