Electrosynthesis of alpha-(silyl)alkylnitriles

被引：3

作者：

Constantieux, T ^{[1
]}

Picard, JP ^{[1
]}

机构：

[1] UNIV BORDEAUX 1,CHIM ORGAN & ORGANOMET LAB,CNRS,URA 35,F-33405 TALENCE,FRANCE

来源：

SYNTHETIC COMMUNICATIONS | 1997年 / 27卷 / 22期

关键词：

D O I：

10.1080/00397919708005913

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Sacrificial anode technique has been used to synthetize title compounds in two different ways. First, use was made of alpha-chloronitriles as the starting materials, zinc as the anode and a THF-HMPA mixture as the solvent. Second, use of an aluminium-made anode, the nitrile being at the same time the substrate and the solvent was shown to be also efficient.

引用

页码：3895 / 3907

页数：13

共 25 条

[1] BRENNER S, 1974, TETRAHEDRON LETT, P1377
[2] SILICON-CARBON MULTIPLE BONDED (P-PI-P-PI) INTERMEDIATES - REACTIONS WITH ACETONITRILE AND ITS DERIVATIVES
BUSH, RD
GOLINO, CM
ROARK, DN
SOMMER, LH
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 59 (OCT1) : C17 - C20
[3] Enamines of acylsilanes: Electrochemical synthesis, structure, and use as a source of alpha-(trimethylsilyl)alkylamines
Constantieux, T
Picard, JP
[J]. ORGANOMETALLICS, 1996, 15 (06) : 1604 - 1609
[4] TRANSFORMATION OF ALPHA-ASSISTED CARBANIONS INTO THE CORRESPONDING TRIMETHYLSILOXY DERIVATIVES USING BIS(TRIMETHYLSILYL) PEROXIDE
DEMBECH, P
GUERRINI, A
RICCI, A
SECONI, G
TADDEI, M
[J]. TETRAHEDRON, 1990, 46 (08) : 2999 - 3006
[5] C-SILYLATION OF COMPOUNDS HAVING NITRILE FUNCTION - SYNTHESIS OF ALPHA-SILYLATED NITRILES
EKOUYA, A
DUNOGUES, J
DUFFAUT, N
CALAS, R
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 148 (03) : 225 - 231
[6] EMDE H, 1977, SYNTHESIS-STUTTGART, P636
[7] Gornowicz G. A., 1971, J AM CHEM SOC, V93, P1714
[8] GRELIER S, 1994, ORGANOMETALLICS, V13, P1378
[9] PALLADIUM CATALYZED COUPLING REACTION OF ALPHA-BROMO KETONES WITH HEXABUTYLDITIN
KOSUGI, M
KOSHIBA, M
SANO, H
MIGITA, T
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1985, 58 (03) : 1075 - 1076
[10] MONOSODIUM ACETANITRILES THEIR PREPARATION PROPERTIES AND REACTIONS
KRUGER, C
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1967, 9 (01) : 125 - &

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