Thermal conductivity of the thermoelectric layered cobalt oxides measured by the Harman method

被引:71
作者
Satake, A
Tanaka, H
Ohkawa, T
Fujii, T
Terasaki, I
机构
[1] Waseda Univ, Dept Appl Phys, Shinjuku Ku, Tokyo 1698555, Japan
[2] Japan Sci & Technol Agcy, CREST, Tokyo 1030027, Japan
关键词
D O I
10.1063/1.1753070
中图分类号
O59 [应用物理学];
学科分类号
摘要
In-plane thermal conductivity of the thermoelectric layered cobalt oxides has been measured using the Harman method, in which thermal conductivity is obtained from temperature gradient induced by applied current. We have found that the charge reservoir block (the block other than the CoO2 block) dominates the thermal conduction, where a nano-block integration concept is effective for material design. We have further found that the thermal conductivity shows a small but finite in-plane anisotropy between a and b axes, which can be ascribed to the misfit structure. (C) 2004 American Institute of Physics.
引用
收藏
页码:931 / 933
页数:3
相关论文
共 22 条
[1]   Sound modes in composite incommensurate crystals [J].
Currat, R ;
Kats, E ;
Luk'yanchuk, I .
EUROPEAN PHYSICAL JOURNAL B, 2002, 26 (03) :339-347
[2]   Large in-plane anisotropy on resistivity and thermopower in the misfit layered oxide Bi2-xPbxSr2Co2Oy [J].
Fujii, T ;
Terasaki, I ;
Watanabe, T ;
Matsuda, A .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 2002, 41 (7A) :L783-L786
[3]   High-temperature thermoelectric properties of NaxCoO2-δ single crystals [J].
Fujita, K ;
Mochida, T ;
Nakamura, K .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2001, 40 (07) :4644-4647
[4]   Bi2Sr2Co2Oy whiskers with high thermoelectric figure of merit [J].
Funahashi, R ;
Shikano, M .
APPLIED PHYSICS LETTERS, 2002, 81 (08) :1459-1461
[5]   Thermoelectric properties of Pb- and Ca-doped (Bi2Sr2O4)xCoO2 whiskers [J].
Funahashi, R ;
Matsubara, I .
APPLIED PHYSICS LETTERS, 2001, 79 (03) :362-364
[6]   An oxide single crystal with high thermoelectric performance in air [J].
Funahashi, R ;
Matsubara, I ;
Ikuta, H ;
Takeuchi, T ;
Mizutani, U ;
Sodeoka, S .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 2000, 39 (11B) :L1127-L1129
[7]   Large thermopower in a metallic cobaltite:: The layered Tl-Sr-Co-O misfit -: art. no. 172101 [J].
Hébert, S ;
Lambert, S ;
Pelloquin, D ;
Maignan, A .
PHYSICAL REVIEW B, 2001, 64 (17)
[8]   Thermoelectric properties of Bi2.3-xPbxSr2.6Co2Oy single crystals [J].
Itoh, T ;
Terasaki, I .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2000, 39 (12A) :6658-6660
[9]   Thermopower enhancement in misfit cobaltites [J].
Maignan, A ;
Hébert, S ;
Pelloquin, D ;
Michel, C ;
Hejtmanek, J .
JOURNAL OF APPLIED PHYSICS, 2002, 92 (04) :1964-1967
[10]   Misfit-layered cobaltite with an anisotropic giant magnetoresistance:: Ca3Co4O9 [J].
Masset, AC ;
Michel, C ;
Maignan, A ;
Hervieu, M ;
Toulemonde, O ;
Studer, F ;
Raveau, B ;
Hejtmanek, J .
PHYSICAL REVIEW B, 2000, 62 (01) :166-175