Synthesis and superparamagnetic property of a Co-Cr Prussian blue analogue nanoparticles inside Nafion membrane

被引：31

作者：

Kosaka, Wataru

Tozawa, Masanori

Hashimoto, Kazuhito

Ohkoshi, Shin-ichi

机构：

[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

[2] Univ Tokyo, Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 09期

关键词：

nanoparticles; Prussian blue analogue; superparamagnetism; blocking temperature; Nafion;

D O I：

10.1016/j.inoche.2006.05.032

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A nanoparticle-type of cobalt hexacyanochromate, (K0.19CoII)-Co-I[Cr-III(CN)(6)](0.73) center dot 4.5H(2)O (particle diameter = 8 +/- 2 nm) is prepared in Nafion. The nanoparticles show the superparamagnetism with blocking temperature (T-B) of 8.5 K and an anisotropy energy barrier of 190 K. Magnetic hysteresis loops are observed below T-B, e.g. 1.2 kOe at 2 K. (C) 2006 Elsevier B.V. All rights reserved.

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收藏

页码：920 / 922

页数：3

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