Non aqueous loading of the mesoporous siliceous MCM-48 matrix with ZnO:: a comparison of solution, liquid and gas-phase infiltration using diethyl zinc as organometallic precursor

被引：16

作者：

Schroeder, Felicitas

Hermes, Stephan

Parala, Harish

Hikov, Todor

Muhler, Martin

Fischer, Roland A.

机构：

[1] Ruhr Univ Bochum, Lehrstuhl Anorgan Chem Organomet & Mat 2, D-44780 Bochum, Germany

[2] Ruhr Univ Bochum, Lehrstuhl Tech Chem, D-4630 Bochum, Germany

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2006年 / 16卷 / 35期

关键词：

D O I：

10.1039/b606814f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Zinc oxide species hosted in the siliceous matrix MCM-48 were prepared by an organometallic route using ZnEt2 as the ZnO precursor. Gas phase as well as liquid phase infiltration of the precursor was studied in detail by ICP-AES, FT-RAIRS, H-1- and C-13-MAS-NMR, PXRD, TEM/EDX and UV - VIS. Highly loaded ZnO@MCM-48 materials with a Zn-content of up to 29.6 wt% were synthesized. A comparison of the different preparation techniques was carried out in order to find a convenient way of preparing ZnO@MCM-48 species for catalytic applications.

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页码：3565 / 3574

页数：10

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