Bridging fullerenes with metals

被引：9

作者：

Chi, DH

Iwasa, Y ^{[1
]}

Chen, XH

Takenobu, T

Ito, T

Mitani, T

Nishibori, E

Takata, M

Sakata, M

Kubozono, Y

机构：

[1] Japan Adv Inst Sci & Technol, Tatsunokuchi, Ishikawa 9231292, Japan

[2] Tohoku Univ, Inst Mat Res, Aoba Ku, Sendai, Miyagi 9808577, Japan

[3] Japan Sci & Technol Corp, CREST, Kawaguchi 3320012, Japan

[4] Univ Sci & Technol China, Struct Res Lab, Hefei 230026, Anhui, Peoples R China

[5] Univ Sci & Technol China, Dept Phys, Hefei 230026, Anhui, Peoples R China

[6] Nagoya Univ, Dept Appl Phys, Nagoya, Aichi 4648062, Japan

[7] Inst Mol Sci, Okazaki, Aichi 4448585, Japan

来源：

CHEMICAL PHYSICS LETTERS | 2002年 / 359卷 / 3-4期

基金：

日本学术振兴会;

关键词：

D O I：

10.1016/S0009-2614(02)00297-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The bonding nature between rare earth metals and fullerene molecules has been investigated. The electron density distribution for nominal Sm3C70, calculated by a maximum entropy method (MEM) based on the Rietveld analysis of synchrotron X-ray diffraction pattern, unambiguously demonstrated a covalent Sm-C bond, which is almost as strong as the interatomic bonding of crystal Si. Furthermore, the Sm bridges two C-70 molecules, producing a C-70-Sm-C-70 dimer structure. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：177 / 183

页数：7

共 25 条

[1] Effect of charge state on polymeric bonding geometry:: The ground state of Na2RbC60 [J].

Bendele, GM ;

Stephens, PW ;

Prassides, K ;

Vavekis, K ;

Kordatos, K ;

Tanigaki, K .

PHYSICAL REVIEW LETTERS, 1998, 80 (04) :736-739

[2] Structural and electronic properties of the noncubic superconducting fullerides A′4C60 (A′= Ba, Sr) [J].

Brown, CM ;

Taga, S ;

Gogia, B ;

Kordatos, K ;

Margadonna, S ;

Prassides, K ;

Iwasa, Y ;

Tanigaki, K ;

Fitch, AN ;

Pattison, P .

PHYSICAL REVIEW LETTERS, 1999, 83 (11) :2258-2261

[3] Synthesis, structure, and transport properties of novel fullerides A3C70 (A = Ba and Sm) [J].

Chen, XH ;

Chi, DH ;

Sun, Z ;

Takenobu, T ;

Liu, ZS ;

Iwasa, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (24) :5729-5732

[4] ELECTRONIC-STRUCTURE OF SUPERCONDUCTING BA6C60 [J].

ERWIN, SC .

PHYSICAL REVIEW B, 1993, 47 (21) :14657-14660

[5] Peculiar covalent bonds in α-rhombohedral boron [J].

Fujimori, M ;

Nakata, T ;

Nakayama, T ;

Nishibori, E ;

Kimura, K ;

Takata, M ;

Sakata, M .

PHYSICAL REVIEW LETTERS, 1999, 82 (22) :4452-4455

[6] Electronic states of Ba6C60 and Sr6C60 fullerides [J].

Gogia, B ;

Kordatos, K ;

Suematsu, H ;

Tanigaki, K ;

Prassides, K .

PHYSICAL REVIEW B, 1998, 58 (03) :1077-1079

[7] ISOLATION OF THE HETEROFULLERENE C59N AS ITS DIMER (C59N)(2) [J].

HUMMELEN, JC ;

KNIGHT, B ;

PAVLOVICH, J ;

GONZALEZ, R ;

WUDL, F .

SCIENCE, 1995, 269 (5230) :1554-1556

[8] NEW PHASES OF C-60 SYNTHESIZED AT HIGH-PRESSURE [J].

IWASA, Y ;

ARIMA, T ;

FLEMING, RM ;

SIEGRIST, T ;

ZHOU, O ;

HADDON, RC ;

ROTHBERG, LJ ;

LYONS, KB ;

CARTER, HL ;

HEBARD, AF ;

TYCKO, R ;

DABBAGH, G ;

KRAJEWSKI, JJ ;

THOMAS, GA ;

YAGI, T .

SCIENCE, 1994, 264 (5165) :1570-1572

[9] Covalent bonds in AlMnSi icosahedral quasicrystalline approximant [J].

Kirihara, K ;

Nakata, T ;

Takata, M ;

Kubota, Y ;

Nishibori, E ;

Kimura, K ;

Sakata, M .

PHYSICAL REVIEW LETTERS, 2000, 85 (16) :3468-3471

[10]

LEBEDKIN S, 1995, TETRAHEDRON LETT, V36, P4971

← 1 2 3 →