Synthesis of novel star-shaped carbazole-functionalized triazatruxenes

被引:35
作者
Feng, Guo-Liang
Lai, Wen-Yong
Ji, Shun-Jun
Huang, Wei
机构
[1] Fudan Univ, IAM, Shanghai 200433, Peoples R China
[2] Nanjing Univ, IAM, Nanjing 210093, Peoples R China
[3] Natl Univ Singapore, Fac Engn, Singapore 117576, Singapore
[4] Soochow Univ, Coll Chem & Chem Engn, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1016/j.tetlet.2006.07.086
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The syntheses of novel well-defined star-shaped carbazole-functionalized triazatruxenes, which consist of six carbazole arms linked with a central triazatruxene core consisting of three carbazoles with one phenyl, are presented. Both 9-hexylcarbazole and 9-phenylcarbazole as arms gave high yields. Their chemical formulas were confirmed by means of H-1 NMR, MALDI-TOF mass spectroscopy, and elementary analysis. The fluorescent spectra showed that these compounds exhibit good blue fluorescence. The maximum fluorescence emission wavelengths were between 420 and 430 nm. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:7089 / 7092
页数:4
相关论文
共 19 条
[1]   Investigating work function tunable hole-injection/transport layers of electrodeposited polycarbazole network thin films [J].
Baba, A ;
Onishi, K ;
Knoll, W ;
Advincula, RC .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (49) :18949-18955
[2]   Carbazole compounds as host materials for triplet emitters in organic light-emitting diodes:: Tuning the HOMO level without influencing the triplet energy in small molecules [J].
Brunner, K ;
van Dijken, A ;
Börner, H ;
Bastiaansen, JJAM ;
Kiggen, NMM ;
Langeveld, BMW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (19) :6035-6042
[3]   2,7-carbazolenevinylene-based oligomer thin-film transistors: High mobility through structural ordering [J].
Drolet, N ;
Morin, JF ;
Leclerc, N ;
Wakim, S ;
Tao, Y ;
Leclerc, M .
ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (10) :1671-1682
[4]   Star-shaped discotic oligomesogens based on radial pentakisphenylethynylbenzene moieties [J].
Grafe, A ;
Janietz, D ;
Frese, T ;
Wendorff, JH .
CHEMISTRY OF MATERIALS, 2005, 17 (20) :4979-4984
[5]   Synthesis and properties of monodisperse oligofluorene-functionalized truxenes: Highly fluorescent star-shaped architectures [J].
Kanibolotsky, AL ;
Berridge, R ;
Skabara, PJ ;
Perepichka, IF ;
Bradley, DDC ;
Koeberg, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (42) :13695-13702
[6]   Monodisperse six-armed triazatruxenes: Microwave-enhanced synthesis and highly efficient pure-deep-blue electroluminescence [J].
Lai, Wen-Yong ;
Zhu, Rui ;
Fan, Qu-Li ;
Hou, Lin-Tao ;
Cao, Yong ;
Huang, Wei .
MACROMOLECULES, 2006, 39 (11) :3707-3709
[7]   A high Tg carbazole-based hole-transporting material for organic light-emitting devices [J].
Li, JY ;
Liu, D ;
Li, YQ ;
Lee, CS ;
Kwong, HL ;
Lee, ST .
CHEMISTRY OF MATERIALS, 2005, 17 (05) :1208-1212
[8]   Novel starburst molecule as a hole injecting and transporting material for organic light-emitting devices [J].
Li, JY ;
Ma, CW ;
Tang, JX ;
Lee, CS ;
Lee, ST .
CHEMISTRY OF MATERIALS, 2005, 17 (03) :615-619
[9]   Polycarbazoles:: 25 years of progress [J].
Morin, JF ;
Leclerc, M ;
Adès, D ;
Siove, A .
MACROMOLECULAR RAPID COMMUNICATIONS, 2005, 26 (10) :761-778
[10]   Syntheses and characterization of electroactive and photoactive 2,7-carbazolenevinylene-based conjugated oligomers and polymers [J].
Morin, JF ;
Drolet, N ;
Tao, Y ;
Leclerc, M .
CHEMISTRY OF MATERIALS, 2004, 16 (23) :4619-4626