Preparation and characterisation of Ag/alumina catalysts for the removal of NOx emissions under oxygen rich conditions

被引:48
作者
Arve, K [1 ]
Capek, L
Klingstedt, F
Eränen, K
Lindfors, LE
Murzin, DY
Dedecek, J
Sobalik, Z
Wichterlová, B
机构
[1] Abo Akad Univ, Lab Ind Chem, Proc Chem Grp, Turku, Finland
[2] J Heyrovsky Inst Phys Chem & Electrochem, CZ-18223 Prague 8, Czech Republic
关键词
Ag/alumina; NO reduction; HC-SCR; lean burn; UV-Vis;
D O I
10.1023/B:TOCA.0000029734.85321.ef
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A highly active silver/alumina catalyst for continuous reduction of NO to nitrogen with octane under lean conditions was prepared. The effect of impregnation time and precursor concentration on the catalyst activity was investigated. The catalyst was characterized by means of XRF, H-2-TPR, and UV-Vis to correlate recorded results with different preparation methods. UV-Vis measurements indicated that the highest and most stable activity is obtained with Ag/alumina exhibiting predominantly mono-atomically dispersed silver.
引用
收藏
页码:91 / 95
页数:5
相关论文
共 11 条
[1]   Supported Ag catalysts for the lean reduction of NO with C3H6 [J].
Bethke, KA ;
Kung, HH .
JOURNAL OF CATALYSIS, 1997, 172 (01) :93-102
[2]  
Eranen K., 2000, 2000012813 SAE
[3]   Characterization of Ag/gamma-Al2O3 catalysts and their lean-NOx properties [J].
Hoost, TE ;
Kudla, RJ ;
Collins, KM ;
Chattha, MS .
APPLIED CATALYSIS B-ENVIRONMENTAL, 1997, 13 (01) :59-67
[4]   Nature and catalytic role of active silver species in the lean NOx reduction with C3H6 in the presence of water [J].
Iglesias-Juez, A ;
Hungría, AB ;
Martínez-Arias, A ;
Fuerte, A ;
Fernández-García, M ;
Anderson, JA ;
Conesa, JC ;
Soria, J .
JOURNAL OF CATALYSIS, 2003, 217 (02) :310-323
[5]   On the promotion of Ag-ZSM-5 by cerium for the SCR of NO by methane [J].
Li, ZJ ;
Flytzani-Stephanopoulos, M .
JOURNAL OF CATALYSIS, 1999, 182 (02) :313-327
[6]   Study of the lean NOx reduction with C3H6 in the presence of water over silver/alumina catalysts prepared from inverse microemulsions [J].
Martínez-Arias, A ;
Fernández-García, M ;
Iglesias-Juez, A ;
Anderson, JA ;
Conesa, JC ;
Soria, J .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2000, 28 (01) :29-41
[7]   Catalytic reduction system of NOx in exhaust gases from diesel engines with secondary fuel injection [J].
Nakatsuji, T ;
Yasukawa, R ;
Tabata, K ;
Ueda, K ;
Niwa, M .
APPLIED CATALYSIS B-ENVIRONMENTAL, 1998, 17 (04) :333-345
[8]  
NIEMI S, 1999, THESIS ABO AKAD, P38
[9]   Study of supported silver states by the method of electron spectroscopy of diffuse reflectance [J].
Pestryakov, AN ;
Davydov, AA .
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1995, 74 (03) :195-199
[10]  
Sydow M, 1996, J INFORM REC, V23, P387