Supercapacitor Devices Based on Graphene Materials

被引:2276
作者
Wang, Yan [1 ,2 ]
Shi, Zhiqiang [3 ]
Huang, Yi [1 ,2 ]
Ma, Yanfeng [1 ,2 ]
Wang, Chengyang [3 ]
Chen, Mingming [3 ]
Chen, Yongsheng [1 ,2 ]
机构
[1] Nankai Univ, Key Lab Funct Polymer Mat, Tianjin 300071, Peoples R China
[2] Nankai Univ, Coll Chem, Inst Polymer Chem, Ctr Nanoscale Sci & Technol, Tianjin 300071, Peoples R China
[3] Tianjin Univ, Sch Chem Engn & Technol, State Educ Minist, Key Lab Green Chem Technol, Tianjin 300072, Peoples R China
关键词
ELECTROCHEMICAL CAPACITORS; CARBON NANOTUBES; ELECTRODE; NITROGEN; SURFACE; PERFORMANCE; PRINCIPLES; NANOSHEETS;
D O I
10.1021/jp902214f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Graphene materials (GMs) as supercapacitor electrode materials have been investigated. GMs are prepared from graphene oxide sheets, and subsequently suffer a gas-based hydrazine reduction to restore the conducting carbon network. A maximum specific capacitance of 205 F/g with a measured power density of 10 kW/kg at energy density of 28.5 Wh/kg in an aqueous electrolyte solution has been obtained. Meanwhile, the supercapacitor devices exhibit excellent long cycle life along with similar to 90% specific capacitance retained after 1200 cycle tests. These remarkable results demonstrate the exciting commercial potential for high performance, environmentally friendly and low-cost electrical energy storage devices based on this new 2D graphene material.
引用
收藏
页码:13103 / 13107
页数:5
相关论文
共 44 条
[1]  
An KH, 2001, ADV FUNCT MATER, V11, P387, DOI 10.1002/1616-3028(200110)11:5<387::AID-ADFM387>3.0.CO
[2]  
2-G
[3]   Nanostructured materials for advanced energy conversion and storage devices [J].
Aricò, AS ;
Bruce, P ;
Scrosati, B ;
Tarascon, JM ;
Van Schalkwijk, W .
NATURE MATERIALS, 2005, 4 (05) :366-377
[4]   Evaluation of solution-processed reduced graphene oxide films as transparent conductors [J].
Becerril, Hdctor A. ;
Mao, Jie ;
Liu, Zunfeng ;
Stoltenberg, Randall M. ;
Bao, Zhenan ;
Chen, Yongsheng .
ACS NANO, 2008, 2 (03) :463-470
[5]   Ultracapacitors: why, how, and where is the technology [J].
Burke, A .
JOURNAL OF POWER SOURCES, 2000, 91 (01) :37-50
[6]   Polyaniline-deposited porous carbon electrode for supercapacitor [J].
Chen, WC ;
Wen, TC ;
Teng, HS .
ELECTROCHIMICA ACTA, 2003, 48 (06) :641-649
[7]   Supercapacitors based on nanostructured carbon electrodes grown by cluster-beam deposition [J].
Diederich, L ;
Barborini, E ;
Piseri, P ;
Podestà, A ;
Milani, P ;
Schneuwly, A ;
Gallay, R .
APPLIED PHYSICS LETTERS, 1999, 75 (17) :2662-2664
[8]   High power density supercapacitors using locally aligned carbon nanotube electrodes [J].
Du, CS ;
Yeh, J ;
Pan, N .
NANOTECHNOLOGY, 2005, 16 (04) :350-353
[9]   Shape-engineerable and highly densely packed single-walled carbon nanotubes and their application as super-capacitor electrodes [J].
Futaba, Don N. ;
Hata, Kenji ;
Yamada, Takeo ;
Hiraoka, Tatsuki ;
Hayamizu, Yuhei ;
Kakudate, Yozo ;
Tanaike, Osamu ;
Hatori, Hiroaki ;
Yumura, Motoo ;
Iijima, Sumio .
NATURE MATERIALS, 2006, 5 (12) :987-994
[10]   The rise of graphene [J].
Geim, A. K. ;
Novoselov, K. S. .
NATURE MATERIALS, 2007, 6 (03) :183-191