Optical properties of self-assembled poly(p-phenylene vinylene) converted at low temperatures

被引：1

作者：

Castro, FA ^{[1
]}

Marletta, A ^{[1
]}

Faria, RM ^{[1
]}

Guimaraes, FEG ^{[1
]}

机构：

[1] USP, IFSC, DFCM, BR-13560970 Sao Carlos, SP, Brazil

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2002年 / 374卷

关键词：

self-assembly; PPV; luminescence; absorption;

D O I：

10.1080/10587250210438

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Self-assembly films of poly(p-phenylene vinylene) (PPV) were prepared by dipping quartz substrates alternately in solutions of the PPV polymer precursor poly(xylylidene tetrahydrothiophenium chloride) (PPV-precursor) and of a sodium salt of dodecylbenzenesulfonic (DBS) acid. The advantage of introducing DBS lies in the possibility of converting films with a high conjugation length at 115 T within only 3 min. By controlling the DBS concentration, symmetrical and non-symmetrical PPV heterostuctures can be realized with a macromolecular manipulation during the dipping direction, leading to enhanced optical proprieties.

引用

页码：421 / 426

页数：6

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