Polymethacrylates with pendant oxadiazole units synthesis and application in organic LEDs

被引:36
作者
Greczmiel, M
Strohriegl, P
Meier, M
Brutting, W
机构
[1] UNIV BAYREUTH,D-95440 BAYREUTH,GERMANY
[2] BAYREUTHER INST MAKROMOL FORSCH,D-95440 BAYREUTH,GERMANY
关键词
D O I
10.1021/ma970226v
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this paper we report an effective synthesis and the characterization of novel 1,3,4-oxadiazole monomers via tetrazole intermediates and their polymerization to side group polymers with laterally fixed charge transport units. The use of these polymers as electron transport layer in light emitting diodes (LED) together with poly (phenylene vinylene) (PPV) leads to improved device performance. The light intensity of our LEDs was increased by a factor of 100 compared to a PPV monolayer diode to 300 Cd/m(2) at 30 V. This corresponds to an external quantum yield of 0.1% using a silver electrode, as cathode.
引用
收藏
页码:6042 / 6046
页数:5
相关论文
共 16 条
  • [1] Efficient synthesis of starburst oxadiazole compounds
    Bettenhausen, J
    Strohriegl, P
    [J]. ADVANCED MATERIALS, 1996, 8 (06) : 507 - +
  • [2] VISIBLE-LIGHT EMISSION FROM SEMICONDUCTING POLYMER DIODES
    BRAUN, D
    HEEGER, AJ
    [J]. APPLIED PHYSICS LETTERS, 1991, 58 (18) : 1982 - 1984
  • [3] POLY(P-PHENYLENEVINYLENE) LIGHT-EMITTING-DIODES - ENHANCED ELECTROLUMINESCENT EFFICIENCY THROUGH CHARGE CARRIER CONFINEMENT
    BROWN, AR
    BRADLEY, DDC
    BURROUGHES, JH
    FRIEND, RH
    GREENHAM, NC
    BURN, PL
    HOLMES, AB
    KRAFT, A
    [J]. APPLIED PHYSICS LETTERS, 1992, 61 (23) : 2793 - 2795
  • [4] BUCHWALD E, 1995, ADV MATER, V7, P839, DOI 10.1002/adma.19950071004
  • [5] BURN PL, 1992, MATER RES SOC SYMP P, V247, P647, DOI 10.1557/PROC-247-647
  • [6] Polymer light emitting diodes
    Greczmiel, M
    Posch, P
    Schmidt, HW
    Strohriegl, P
    Buchwald, E
    Meier, M
    Riess, W
    Schwoerer, M
    [J]. MACROMOLECULAR SYMPOSIA, 1996, 102 : 371 - 380
  • [7] HAMADA Y, 1995, APPL PHYS LETT, V66, P3433
  • [8] RINGOFFNUNGEN DER AZOLE .2. DIE BILDUNG VON 1.3.4-OXIDIAZOLEN BEI DER ACYLIERUNG 5-SUBSTITUIERTER TETRAZOLE
    HUISGEN, R
    SAUER, J
    STURM, HJ
    MARKGRAF, JH
    [J]. CHEMISCHE BERICHTE-RECUEIL, 1960, 93 (09): : 2106 - 2124
  • [10] KRAFT A, 1996, J CHEM SOC CHEM COMM, P77