Entangled Two-Dimensional Coordination Networks: A General Survey

被引：260

作者：

Carlucci, Lucia ^{[1
]}

Ciani, Gianfranco ^{[1
]}

Proserpio, Davide M. ^{[1
,2
]}

Mitina, Tatiana G. ^{[2
]}

Blatov, Vladislav A. ^{[2
,3
]}

机构：

[1] Univ Milan, Dipartimento Chim, I-20133 Milan, Italy

[2] Samara State Univ, Samara Ctr Theoret Mat Sci, Samara 443011, Russia

[3] King Abdulaziz Univ, Dept Chem, Fac Sci, Jeddah 21589, Saudi Arabia

来源：

CHEMICAL REVIEWS | 2014年 / 114卷 / 15期

基金：

俄罗斯基础研究基金会;

关键词：

METAL-ORGANIC FRAMEWORKS; INORGANIC 3D NETWORKS; ONE-POT SYNTHESIS; CRYSTAL-STRUCTURES; SINGLE-CRYSTAL; SUPRAMOLECULAR ISOMERS; INTERPENETRATING STRUCTURES; STRUCTURAL-CHARACTERIZATION; POLYCATENANE-LIKE; SPHERE PACKINGS;

D O I：

10.1021/cr500150m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Many of the reported species exhibit the intriguing feature of interpenetration or other types of entanglements. The properties of these materials are related not only to their molecular structures but also to the topology of the individual networks as well as to the way in which the individual nets are entangled. Different synthetic procedures have been developed to attain a certain control of entanglement in coordination networks, and recently some reviews have appeared that are focused on factors governing the entanglements, having in mind their potential applications. However, these analyses are mostly devoted to 3D networks thanks to the great wealth of data on interpenetration. Simplification of a network that contains 2-loops can lead to complete disappearance of the entanglement, and therefore such networks were picked out into a separate group.

引用

页码：7557 / 7580

页数：24

共 192 条

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