Ti 2p and O 1s core levels and chemical bonding in titanium-bearing oxides

被引：290

作者：

Atuchin, Victor V. ^{[1
]}

Kesler, Valery G.

Pervukhina, Natalia V.

Zhang, Zhaoming

机构：

[1] Russian Acad Sci, Inst Semicond Phys, SB, Lab Opt Mat & Struct, Novosibirsk 630090, Russia

[2] Russian Acad Sci, Inst Semicond Phys, SB, Ctr Tech, Novosibirsk 630090, Russia

[3] Russian Acad Sci, Inst Inorgan Chem, SB, Lab Crystal Chem, Novosibirsk 630090, Russia

[4] Australian Nucl Sci & Technol Org, Menai, NSW 2234, Australia

来源：

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 2006年 / 152卷 / 1-2期

关键词：

titanates; chemical bonding; XPS;

D O I：

10.1016/j.elspec.2006.02.004

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

A set of available experimental data on the binding energies of Ti 2p(3/2) and 0 Is core levels in titanium-bearing oxides has been presented by using the binding energy difference (0 1s-Ti 2P(3/2)) as a robust parameter to characterize these compounds. An empirical relationship between the (0 1s-Ti 2P(3/2)) values measured with XPS and the mean chemical bond length L(Ti-O) in these crystals has been discussed for Ti4+-compounds. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：18 / 24

页数：7

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