Anisotropic coarsening of two-dimensional surface domains in copolymer thin films

被引:31
作者
Heier, J [1 ]
Sivaniah, E [1 ]
Kramer, EJ [1 ]
机构
[1] Univ Calif Santa Barbara, Dept Mat, Santa Barbara, CA 93106 USA
关键词
D O I
10.1021/ma990916u
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
We have investigated by scanning force microscopy the growth of surface relief structures on thin diblock copolymer films for a infinity x infinity geometry (homogeneous substrate) and a L x infinity geometry (heterogeneous substrate). We characterize the growth by a length scale obtained from the correlation function describing the fluctuations. Two-dimensional viscous flow within a continuous layer dominates the process. On the homogeneous substrate we find a power law growth with an exponent of alpha = 2/3, while the growth on the stripe pattern in a direction parallel to the stripes is characterized by an exponent that is much lower.
引用
收藏
页码:9007 / 9012
页数:6
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