An unprecedented bridging [Ag2(NO3)6]4- anion as a component of an infinite silver(I) molecular ladder incorporating a dinuclear cationic silver complex of a bis-dipyridylamine ligand

被引:18
作者
Antonioli, Bianca
Clegg, Jack K.
Bray, David J.
Gloe, Kerstin [1 ]
Gloe, Karsten
Hesske, Holger
Lindoy, Leonard F.
机构
[1] Univ Sydney, Sch Chem, Ctr Heavy Met Res, Sydney, NSW 2006, Australia
[2] Tech Univ Dresden, Dept Chem, D-01062 Dresden, Germany
来源
CRYSTENGCOMM | 2006年 / 8卷 / 10期
关键词
D O I
10.1039/b611270f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The interaction of silver( I) nitrate with the polypyridyl ligand (I) formed from two dipyridylamine units joined at their secondary amines by a 2,6-lutidinyl bridge results in a molecular ladder motif that consists of pairs of cationic [Ag-2(L) MeCN](2+) units bridged by an unprecedented [Ag-2(NO3) (6)](4-) anion.
引用
收藏
页码:748 / 750
页数:3
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