Ultracold Rb-OH collisions and prospects for sympathetic cooling

We compute ab initio cross sections for cold collisions of Rb atoms with OH radicals. We predict collision rate constants of order 10(-11) cm(3)/s at temperatures in the range 10-100 mK at which molecules have already been produced. However, we also find that in these collisions the molecules have a strong propensity for changing their internal state, which could make sympathetic cooling of OH in a Rb buffer gas problematic in magnetostatic or electrostatic traps.